A simple amine protection strategy for olefin metathesis reactions.
نویسندگان
چکیده
Acyclic diamines are valuable feedstocks for polyamide synthesis. Ruthenium-alkylidene catalysed cross metathesis of amino alkenes is problematic and acyl derivatisation can result in less efficient syntheses, poor catalyst turnover and isomerisation. Temporary amine masking via stable and soluble ammonium salts delivers cyclic and acyclic aminoalkenes in high yield and purity.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 2 شماره
صفحات -
تاریخ انتشار 2011